XElement xmlTree = new XElement("Root",
new XElement("Child1", "child1 content"),
new XElement("Child2", "child2 content"),
new XElement("Child3", "child3 content"),
new XElement("Child4", "child4 content"),
new XElement("Child5", "child5 content")
);
XElement child3 = xmlTree.Element("Child3");
child3.ReplaceWith(
new XElement("NewChild", "new content")
);
Console.WriteLine(xmlTree);