<Canvas Height="200" Width="200">

  <!-- Rotates the Polyline 45 degrees about the point (0,0). -->
  <Polyline Points="25,25 0,50 25,75 50,50 25,25 25,0" 
    Stroke="Blue" StrokeThickness="10"
    Canvas.Left="75" Canvas.Top="50">
    <Polyline.RenderTransform>
      <RotateTransform CenterX="0" CenterY="0" Angle="45" />
    </Polyline.RenderTransform>
  </Polyline>
</Canvas>

// Create a Polyline.
Polyline polyline1 = new Polyline();
polyline1.Points.Add(new Point(25, 25));
polyline1.Points.Add(new Point(0, 50));
polyline1.Points.Add(new Point(25, 75));
polyline1.Points.Add(new Point(50, 50));
polyline1.Points.Add(new Point(25, 25));
polyline1.Points.Add(new Point(25, 0));
polyline1.Stroke = Brushes.Blue;
polyline1.StrokeThickness = 10;

// Create a RotateTransform to rotate
// the Polyline 45 degrees about its
// top-left corner.
RotateTransform rotateTransform1 =
    new RotateTransform(45);
polyline1.RenderTransform = rotateTransform1;

// Create a Canvas to contain the Polyline.
Canvas canvas1 = new Canvas();
canvas1.Width = 200;
canvas1.Height = 200;
Canvas.SetLeft(polyline1, 75);
Canvas.SetTop(polyline1, 50);
canvas1.Children.Add(polyline1);

<Canvas Height="200" Width="200">

  <!-- Rotates the Polyline 45 degrees about the point (25,50). -->
  <Polyline Points="25,25 0,50 25,75 50,50 25,25 25,0" 
    Stroke="Blue" StrokeThickness="10"
    Canvas.Left="75" Canvas.Top="50">
    <Polyline.RenderTransform>
      <RotateTransform CenterX="25" CenterY="50" Angle="45" />
    </Polyline.RenderTransform>
  </Polyline>
</Canvas>

// Create a Polyline.
Polyline polyline2 = new Polyline();
polyline2.Points = polyline1.Points;
polyline2.Stroke = Brushes.Blue;
polyline2.StrokeThickness = 10;

// Create a RotateTransform to rotate
// the Polyline 45 degrees about the
// point (25,50).
RotateTransform rotateTransform2 =
    new RotateTransform(45);
rotateTransform2.CenterX = 25;
rotateTransform2.CenterY = 50;
polyline2.RenderTransform = rotateTransform2;

// Create a Canvas to contain the Polyline.
Canvas canvas2 = new Canvas();
canvas2.Width = 200;
canvas2.Height = 200;
Canvas.SetLeft(polyline2, 75);
Canvas.SetTop(polyline2, 50);
canvas2.Children.Add(polyline2);