Dim site As SPSite = SPContext.Current.Site
Dim targetWeb As SPWeb = site.AllWebs("Site_Name/Subsite_Name")
Dim docLibFolder As SPFolder = targetWeb.Folders("Shared Documents")
Dim docLibFiles As SPFileCollection = docLibFolder.Files
Dim i As Integer
For i = 0 To docLibFiles.Count - 1
docLibFiles(i).CheckOut()
Next i