This function may be called anywhere within the scope of a CATCH block.
ERROR_NUMBER returns the error number regardless of how many times it is run, or where it is run within the scope of the CATCH block. This is in contrast to @@ERROR, which only returns the error number in the statement immediately after the one that causes an error, or the first statement of a CATCH block.
In nested CATCH blocks, ERROR_NUMBER returns the error number specific to the scope of the CATCH block in which it is referenced. For example, the CATCH block of an outer TRY...CATCH construct could have a nested TRY...CATCH construct. Within the nested CATCH block, ERROR_NUMBER returns the number from the error that invoked the nested CATCH block. If ERROR_NUMBER is run in the outer CATCH block, it returns the number from the error that invoked that CATCH block.