The SyncObjects object contains a set of SyncObject objects representing the Send\Receive groups for a user.
Using the SyncObjects Object
Set mySyncObjects = Application.GetNameSpace("MAPI").SyncObjects
The SyncObjects object is read-only. You cannot add an item to the collection. However, note that you can add one Send/Receive group using the AppFolders property which will create a Send/Receive group called Application Folders.